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《能源前沿(英文)》 doi: 10.1007/s11708-023-0898-0
关键词: carbon dioxide electroreduction electrochemistry co-electrodeposition intermetallic catalysts value-added chemicals
Effects of additive NaI on electrodeposition of Al coatings in AlCl
Tianyu Yao, Haiyan Yang, Kui Wang, Haiyan Jiang, Xiao-Bo Chen, Hezhou Liu, Qudong Wang, Wenjiang Ding
《化学科学与工程前沿(英文)》 2021年 第15卷 第1期 页码 138-147 doi: 10.1007/s11705-020-1935-8
电沉积Mo和Mo-Co合金纳米线用于互联电阻的电阻率改性 Article
Jun Hwan Moon, Taesoon Kim, Youngmin Lee, Seunghyun Kim, Yanghee Kim, Jae-Pyoung Ahn, Jungwoo Choi, Hyuck Mo Lee, Young Keun Kim
《工程(英文)》 2024年 第32卷 第1期 页码 128-138 doi: 10.1016/j.eng.2023.07.017
Achieving historically anticipated improvement in the performance of integrated circuits is challenging, due to the increasing cost and complexity of the required technologies with each new generation. To overcome this limitation, the exploration and development of novel interconnect materials and processes are highly desirable in the microelectronics field. Molybdenum (Mo) is attracting attention as an advanced interconnect material due to its small resistivity size effect and high cohesive energy; however, effective processing methods for such materials have not been widely investigated. Here, we investigate the electrochemical behavior of ions in the confined nanopores that affect the electrical properties and microstructures of nanoscale Mo and Mo–Co alloys prepared via template-assisted electrodeposition. Additives in an electrolyte allow the deposition of extremely pure metal materials, due to their interaction with metal ions and nanopores. In this study, boric acid and tetrabutylammonium bisulfate (TBA) were added to an acetate bath to inhibit the hydrogen evolution reaction. TBA accelerated the reduction of Mo at the surface by inducing surface conduction on the nanopores. Metallic Mo nanowires with a 130 nm diameter synthesized through high-aspect-ratio nanopore engineering exhibited a resistivity of (63.0 ± 17.9) μΩ·cm. We also evaluated the resistivities of Mo–Co alloy nanowires at various compositions toward replacing irreducible conventional barrier/liner layers. An intermetallic compound formed at an Mo composition of 28.6 at%, the resistivity of the Mo–Co nanowire was (58.0 ± 10.6) μΩ·cm, indicating its superior electrical and adhesive properties in comparison with those of conventional barriers such as TaN and TiN. Furthermore, density functional theory and non-equilibrium Green’s function calculations confirmed that the vertical resistance of the via structure constructed from Mo-based materials was 21% lower than that of a conventional Cu/Ta/TaN structure.
关键词: Molybdenum Molybdenum–cobalt Interconnect Microstructure Electrodeposition Density functional theory
《化学科学与工程前沿(英文)》 2022年 第16卷 第3期 页码 376-383 doi: 10.1007/s11705-021-2062-x
关键词: interface engineering CoS/CeO2 electrodeposition electrocatalyst oxygen evolution reaction
Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths
Hanbin Zheng, Christine Picard, Serge Ravaine
《化学科学与工程前沿(英文)》 2018年 第12卷 第2期 页码 247-251 doi: 10.1007/s11705-018-1710-2
关键词: nanostructuration light absorption coating gold electrodeposition anodization
Decoration of vertically aligned TiO
Heba ALI, N. ISMAIL, M. S. AMIN, Mohamed MEKEWI
《能源前沿(英文)》 2018年 第12卷 第2期 页码 249-258 doi: 10.1007/s11708-018-0547-1
关键词: titanium dioxide nanotube arrays potentiostaticanodization electrodeposition method tungsten oxide photoelectrochemical water splitting
CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage
《能源前沿(英文)》 2023年 第17卷 第3期 页码 428-445 doi: 10.1007/s11708-023-0865-9
关键词: shale gas gas injection competitive adsorption enhanced shale gas recovery CO2 geological storage
CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2
Kechao Zhao,Zhenhua Li,Li Bian
《化学科学与工程前沿(英文)》 2016年 第10卷 第2期 页码 273-280 doi: 10.1007/s11705-016-1563-5
关键词: Mn promotion nickel catalysts CO2 methanation co-methanation of CO and CO2
An investigation of the CHOH and CO selectivity of CO hydrogenation over Cu–Ce–Zr catalysts
《化学科学与工程前沿(英文)》 2022年 第16卷 第6期 页码 950-962 doi: 10.1007/s11705-022-2162-2
关键词: CO2 hydrogenation Cu–Ce–Zr hydroxyls CO/CH3OH selectivity
《化学科学与工程前沿(英文)》 2022年 第16卷 第7期 页码 1139-1148 doi: 10.1007/s11705-021-2111-5
关键词: CO oxidation heterogeneous catalysis metal-organic framework NH2 functional group PdNi
Reduction potential of the energy penalty for CO capture in CCS
《能源前沿(英文)》 2023年 第17卷 第3期 页码 390-399 doi: 10.1007/s11708-023-0864-x
关键词: CO2 capture and storage (CCS) CO2 separation energy penalty
A coal-fired power plant integrated with biomass co-firing and CO capture for zero carbon emission
《能源前沿(英文)》 2022年 第16卷 第2期 页码 307-320 doi: 10.1007/s11708-021-0790-8
关键词: coal-fired power plant biomass co-firing CO2 capture zero carbon emission performance evaluation
以净零排放为目标的封存驱动型CO2提高采收率方法 Article
刘月亮, 芮振华
《工程(英文)》 2022年 第18卷 第11期 页码 79-87 doi: 10.1016/j.eng.2022.02.010
关键词: CO2 EOR CO2净排放量 二甲醚 封存驱动型CO2 EOR CO2封存
李姜辉,李鹏春,李彦尊,童峰
《中国工程科学》 2023年 第25卷 第2期 页码 173-186 doi: 10.15302/J-SSCAE-2023.07.015
离岸碳捕集、利用与封存(CCUS)技术是沿海国家或地区通过工程方式为实现CO2减排而发展起来的解决方案与技术体系;相对于陆上离岸CCUS技术指从沿海大型或近海碳排放源捕集CO2,加压并运输至离岸封存平台后注入海底地质储层中,实现CO2与大气永久隔离或利用其生产价值产品的过程。本文概要回顾了全球及我国离岸CCUS技术的发展需求与产业现状,分析了发展离岸CCUS的技术性和社会性价值;梳理总结了代表性的离岸CCUS技术发展路线及其态势,如CO2工厂捕集、CO2管道运输、CO2海底咸水层封存与驱油利用、CO2化学利用以及其他技术架构。
Ni-Co bimetallic catalyst for CH
Xiaohong LI, Jun AI, Wenying LI, Dongxiong LI
《化学科学与工程前沿(英文)》 2010年 第4卷 第4期 页码 476-480 doi: 10.1007/s11705-010-0512-y
关键词: Ni-Co bimetallic catalyst composite support CH4 reforming with CO2
标题 作者 时间 类型 操作
Electrochemical CO reduction to C products over CuZn intermetallic catalysts synthesized by electrodeposition
期刊论文
Effects of additive NaI on electrodeposition of Al coatings in AlCl
Tianyu Yao, Haiyan Yang, Kui Wang, Haiyan Jiang, Xiao-Bo Chen, Hezhou Liu, Qudong Wang, Wenjiang Ding
期刊论文
电沉积Mo和Mo-Co合金纳米线用于互联电阻的电阻率改性
Jun Hwan Moon, Taesoon Kim, Youngmin Lee, Seunghyun Kim, Yanghee Kim, Jae-Pyoung Ahn, Jungwoo Choi, Hyuck Mo Lee, Young Keun Kim
期刊论文
Interface engineering for enhancing electrocatalytic oxygen evolution reaction of CoS/CeO heterostructures
期刊论文
Nanostructured gold films exhibiting almost complete absorption of light at visible wavelengths
Hanbin Zheng, Christine Picard, Serge Ravaine
期刊论文
CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2
Kechao Zhao,Zhenhua Li,Li Bian
期刊论文
Conversion of CO into CO by high active and stable PdNi nanoparticles supported on a metal-organic framework
期刊论文
A coal-fired power plant integrated with biomass co-firing and CO capture for zero carbon emission
期刊论文